Mineralogical sources of the buffer capacity in a granite catchment determined by strontium isotopes     

Christina Weyer  Gunnar Lischeid  Luc Aquilina  Anne-Catherine Pierson-Wickmann  Charlotte Martin 《Applied Geochemistry》2008

The role of different minerals in base cation release and thus the increase of buffering capacity of groundwater against acid deposition is controversially discussed in the literature. The ⁸⁷Sr/⁸⁶Sr ratios and base cation concentration were investigated in whole rock leachates, mineral separates, precipitation, soil solution, groundwater and stream water samples in the Lehstenbach catchment (Germany) to identify the weathering sequence of the granite bedrock. Three different approaches were followed in parallel. It was assumed that the contribution of different minerals to base cation supply of the groundwater with increasing weathering intensity would be observed by investigating (1) unweathered rock leachates, deep groundwater and shallow groundwater, (2) groundwater samples from new groundwater wells, reflecting the initial weathering of the drilled bedrock, and groundwater from wells that were drilled in 1988, (3) stream water during baseflow, dominated by deep groundwater, and stream water during high flow, being predominantly shallow groundwater. Whereas the first approach yielded consistent patterns, there was some evidence that groundwater from the new wells initially reflected contamination by the filter gravel rather than cation release in an initial stage of weathering. Time series samples of stream water and groundwater solute concentrations and isotope ratios turned out to reflect varying fractions of soil water and precipitation water at baseflow and high flow conditions rather than varying contributions of different minerals that prevail at different stages of granite weathering.  相似文献   

Aspects of conservation in the excavation site of the Athribis temple in Egypt     

Hans Leisen  Esther von Plehwe-Leisen  Christina Verbeek  Christine Jürgens  Sabine Krause 《Environmental Geology》2008,56(3-4):689-697

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On the geologic structure of the Explora Escarpment (Weddell Sea,Antarctica) revealed by satellite and Shipboard data evaluation     

Ute Christina Herzfeld  Arnold L. Brodscholl 《Marine Geophysical Researches》1994,16(5):325-345

Bathymetric, gravity, and magnetic data from Antarctic expeditions with RV POLARSTERN and satellite altimeter data from the Geosat Geodetic Mission are analysed using methods from geostatistics and geophysical inverse theory.The Explora Escarpment represents the edge between the Antarctic Continental Shelf and the Weddell Abyssal Plain. It is an important link in the reconstruction of Gondwana breakup, but a feature as large as the 2000 m deep Wegener Canyon was only discovered in 1984, when extensive bathymetric, gravimetric, and magnetic surveys with RV POLARSTERN began.Geostatistics, the theory of regionalized variables, is applied to integrate dense surveys of Wegener Canyon and sparse observations in adjacent areas into maps with full coverage of the 230 km by 330 km area at 10°–20° W/70°–72° S. The resultant highresolution bathymetric and gravity maps reveal detailed structures of the Explora Escarpment. Using geophysical inversion, the gravity terrain effect is calculated. Satellite data are used for their better coverage, but have much lower resolution. Nevertheless, the structures of Wegener Canyon and other more prominent features appear with surprisingly good correlation also in the Geosat altimeter data. While it was initially supposed that Wegener Canyon is purely an erosional structure, the magnetic map now provides evidence of the canyon's tectonic origin.  相似文献   

Detection of DNA damage in mussels and sea urchins exposed to crude oil using comet assay     

Taban IC  Bechmann RK  Torgrimsen S  Baussant T  Sanni S 《Marine environmental research》2004,58(2-5):701-705

The single-cell microgel electrophoresis assay or the comet assay was used to evaluate DNA damage of dispersed crude oil on sea urchins (Strongylocentrotus droebachiensis) and mussels (Mytilus edulis L.). Sea urchins were exposed to 0.06 and 0.25 mg/L dispersed crude oil in a continuous flow system, while the mussels were exposed to 0.015, 0.06 and 0.25 mg/L dispersed crude oil. Sea urchin coelomocytes and mussel haemocytes were sampled after 4 and 5 weeks exposure, respectively. In the sea urchin coelomocytes, there was a significant concentration-related increase in the percentage of DNA in comet tail. In mussel haemocytes, there was a significantly higher percentage of DNA in comet tail for all treatments compared to the control. The responses were concentration-related up to 0.06 mg/L oil. The two highest exposure concentrations of mussels were not significantly different from each other. These results indicate that the comet assay can be used for biomonitoring of DNA damage in marine invertebrates following oil contamination.  相似文献   

Chemical composition of hard- and softrock groundwaters from central Norway with special consideration of fluoride and Norwegian drinking water limits     

O. M. Sæther  C. Reimann  B. O. Hilmo  E. Taushani 《Environmental Geology》1995,26(3):147-156

Groundwaters from crystalline and metamorphic rocks (hardrocks) and from Quaternary deposits, i.e., alluvial and glacial deposits (softrocks) from the counties of Nord-Trøndelag and Sør-Trøndelag were analyzed for major and minor elements and ions including fluoride. The median concentration of F^– in water from the hardrock aquifers is 0.28 mg/l (14.7 eq/l) in contrast to water from softrock aquifers in which it is found to be 0.05 mg/1 (2.6 eq/l). More importantly, ca. 15% of the locations where water was abstracted from hardrock wells contain 1.5 mg/l (78.9 eq/l) F^– or more. Thus, 15% of all hardrock wells returned F^– results that are at or above the maximum recommended value for drinking water. Of the softrock wells, none are above 1 mg/l. Geologists would normally expect higher F^–contents in groundwaters derived from acid rocks, e.g., in granitic or gneissic areas. When comparing the host lithology with the observed F^–contents, however, no clear relationship between F^– content and lithology is visible. The highest observed F^– values actually occur in gneissic host rocks. However, wells drilled in amphibolites/greenstones, mica schists, calcareous rocks, and sedimentary rocks all returned some analytical results above 1.5 mg/l F^–. These results suggest that all hardrock wells drilled should be tested for F^– and the users informed about the results and advised to take any necessary precautions. When applying the recently proposed Norwegian drinking water limits to our data, 51% of all softrock well waters and 56% of all hardrock well waters are unfit for consumption without prior treatment, although we analyzed only for about half of the proposed elements/parameters. This result seriously questions the concept of fixed action levels—many of them with totally unproven health implications—for so many parameters/elements for hardrock groundwaters.  相似文献   

Single frequency processing of Ørsted GPS radio occultation measurements     

Georg Bergeton Larsen  Stig Syndergaard  Per Høeg  Martin Bjært Sørensen 《GPS Solutions》2005,9(2):144-155

The Global Positioning System (GPS) radio occultation measurements obtained using the TurboRogue GPS receiver on the Danish satellite Ørsted have been processed using the single frequency method. Atmospheric profiles of refractivity and temperature are derived and validated against numerical weather prediction data from the European Centre for Medium-Range Weather Forecast (ECMWF). Results from the Ørsted GPS measurement campaign in February 2000 indicate that the single frequency method can provide retrievals with accuracy comparable to that of using two frequencies. From comparisons between measured dry temperature profiles and corresponding dry temperature profiles derived from ECMWF analysis fields, we find a mean difference of less than 0.5 K and a standard deviation of 2–4 K between 500 and 30 hPa in height. Above 30 hPa the impact of the ionosphere becomes more dominant and more difficult to eliminate using the single frequency method, and the results show degraded accuracy when compared to previous analysis results of occultation data from other missions using the dual frequency method. At latitudes less than 40° (denoted low latitudes), the standard deviation is generally smaller than at latitudes higher than 40° (denoted high latitudes). A small temperature bias is observed centered at 200 hPa for low latitudes and at 300 hPa for high latitudes. This indicates that the ECMWF analyses do not adequately resolve the tropopause temperature minimum. In the lowest part of the troposphere an observed warm bias is thought to be due to erroneous tracking of the GPS signal in cases of atmospheric multipath propagation.  相似文献   

Optimized Seismic Threshold Monitoring – Part 2: Teleseismic Processing     

T. Kværna  F. Ringdal  J. Schweitzer  L. Taylor 《Pure and Applied Geophysics》2002,159(5):989-1004

v--vThis second paper (Part 2) pertaining to optimized site-specific threshold monitoring addresses the application of the method to regions covered by a teleseismic or a combined regional-teleseismic network. In the first paper (Part 1) we developed the method for the general case, and demonstrated its application to an area well-covered by a regional network (the Novaya Zemlya nuclear test site). In the present paper, we apply the method to the Indian and Pakistani nuclear test sites, and show results during the periods of nuclear testing by these two countries in May 1998. Since the coverage by regional stations in these areas is poor, an optimized approach requires the use of selected, high-quality stations at teleseismic distances.¶To optimize the threshold monitoring of these test sites, we use as calibration events either one of the nuclear explosions or a nearby earthquake. From analysis of the calibration events we derive values for array beamforming steering delays, filter bands, short-term averages (STA) lengths, phase travel times (P waves), and amplitude-magnitude relationships for each station. By applying these parameters, we obtain a monitoring capability of both test sites ranging from m_b 2.8-3.0 using teleseismic stations only. When including the nearby Nilore station to monitor the Indian tests, we show that the threshold can be reduced by about 0.4 magnitude units. In particular, we demonstrate that the Indian tests on 13 May, 1998, which were not detected by any known seismic station, must have corresponded to a magnitude (m_b) of less than 2.4.¶We also discuss the effect of a nearby aftershock sequence on the monitoring capability for the Pakistani test sites. Such an aftershock sequence occurred in fact on the day of the last Pakistani test (30 May, 1998), following a large (m_b 5.5) earthquake in Afghanistan located about 1100 km from the test site. We show that the threshold monitoring technique has sufficient resolution to suppress the signals from these interfering aftershocks without significantly affecting the true peak of the nuclear explosion on the threshold trace.  相似文献   

Adaptive Multiscale Permeability Estimation     

Alv-Arne Grimstad  Trond Mannseth  Geir Nævdal  Hege Urkedal 《Computational Geosciences》2003,7(1):1-25

With multiscale permeability estimation one does not select parameterization prior to the estimation. Instead, one performs a hierarchical search for the right parameterization while solving a sequence of estimation problems with an increasing parameterization dimension. In some previous works on the subject, the same refinement is applied all over the porous medium. This may lead to over-parameterization, and subsequently, to unrealistic permeability estimates and excessive computational work. With adaptive multiscale permeability estimation, the new parameterization at an arbitrary stage in the estimation sequence is such that new degrees of freedom are not necessarily introduced all over the porous medium. The aim is to introduce new degrees of freedom only where it is warranted by the data. In this paper, we introduce a novel adaptive multiscale estimation. The approach is used to estimate absolute permeability from two-phase pressure data in several numerical examples.  相似文献   

Small-scale vegetation dynamics in semi-arid steppe in Inner Mongolia     

Wei Zhang  Christina Skarpe 《Journal of Arid Environments》1996,34(4):421-439

Small-scale vegetation dynamics were followed for ecotones and in uniform stands inArtemisia-dominated steppe vegetation under grazing and when recovering from heavy grazing. Species composition was followed annually for 5 years in 1 m²and 0·25 m²plots for (1) presence–absence; (2) density; and (3) biomass.More rapid vegetation dynamics, in terms of change of type of vegetation and distance moved in DCA species space between sampling occasions, were observed in smaller plots and in early seral stages, where species were few and alpha diversity low. Only the plots recently protected from grazing showed a directional vegetation change; those protected for more than 3 years and those under continued grazing showed, at this scale, non-directional dynamics.  相似文献   

A Local Example of Land‐Use Change: Southern Illinois—1807, 1938, and 1993*     

Leslie A. Duram  Jon Bathgate  Christina Ray 《The Professional geographer》2004,56(1):127-140

This article provides an analysis of a wetland site in southern Illinois from presettlement to the present. The study area is part of the Cache River‐Cypress Creek Wetland, which has international importance, as recognized by the Ramsar Convention on Wetlands. Land‐cover data for 1807, 1938, and 1993 were created and analyzed with a geographic information system (GIS). Land‐use change by topographic setting (uplands, transitional, and bottomlands) and soil productivity was quantified and studied. Interviews with local experts informed this analysis. Results illustrate the complexity of environmental change and its driving forces. First, notable forest and swamp acreage was converted to cropland between 1807 and 1938 and, to a lesser degree, from 1938 to 1993. Second, there were land‐use variations by topographic region. Between 1807 and 1938, the largest transformation occurred in the uplands, with substantial acreage converted from forest to cropland. Between 1938 and 1993, however, agriculture decreased in the upland areas as hilly areas reverted to forest cover. At the same time, agriculture expanded in the bottomlands as this land was drained for farming. Third, there are interesting patterns within these categories of land‐use change, as soil productivity is an indicator of what lands were taken out of cropland and converted back to grassland and forest.  相似文献